Sunday, 23 November 2014

The use of ethanol as an alternative fuel and the success of current use


Why must petroleum be replaced?
There is a limited supply of petroleum in the world. Local reserves of oil are likely to run out within the next 20-30 years(Conquering Chemistry, Smith, 2005).Transportation as well as a few more minor contribution are quickly consuming what petroleum still exists. A primary example of this is the the usage in the united states where transportation is responsible for three quarters of petroleum consumption. A major disadvantage of the global reliance on petroleum are trade deficits, supply disruption and price changes.
Why ethanol?
Ethanol is used extensively as a solvent in the manufacture of varnishes and perfumes; as a preservative for biological specimens; in the preparation of essences and flavorings; in many medicines and drugs; as a disinfectant and in tinctures; and as a fuel and gasoline additive The following data are from the Renewable Fuels Association's 2013 Ethanol Industry Outlook (PDF) and show why ethanol is a suitable alternative to petroleum:









Advantages
  • Ethanol can operate as a fuel
Ethanol helps in reducing the reliance on imported crude oil- a major contributor to greenhouse gas emissions. Ethanol is used as a solvent and as a starting point for making many other chemicals such as acetic acid and ethyl acetate. It is a renewable resource which is important for the production of transportation fuels. It is commonly known for low level blends such as E10 which is composed of 10% ethanol and 90% gasoline, and the high level blends such as E85 which is a gasoline-ethanol blend containing 51% to 83% ethanol.

Ethanol can be blended with gasoline at levels ranging from 5% to 25% which means it reduces the use of petroleum and hence tail pipe emissions.  Pure ethanol is considered to be anything between 85% and 100% ethanol. This would further reduce the reliance of petroleum, however achieving 100% purity is very difficult and even the more achievable amount of 85% purity can only be used on specially designed engines.
The technology to produce Ethanol is already known and was showed in the first section. With the use of this fuel the reliance on oil is less which can be seen by the following graph.


  • Renewable properties
Ethanol is made from carbon dioxide water and sunlight via glucose. The fact that the sugar or starch used to make ethanol is from plants means that it is a renewable and sustainable energy source. When the Ethanol is burnt it returns to carbon dioxide, and water so it has the potential to convert back into ethanol.Below is a diagram of "the ethanol cycle"(Page 34, Figure 1.10, conquering chemistry HSC Course, 4th Edition, Roland Smith):

When ethanol from plants is burnt, the carbon dioxide released is equivalent to the amount absorbed by the plant during photosynthesis which makes the sugar. As a result the use of plant-derived ethanol  does not contribute to the "Greenhouse Effect".
  • Production of ethanol will create more job opportunities. The impact Ethanol will have economically with the United States as an example is depicted in the graph below. 


  • Ethanol is an easily transportable liquid which readily burns:


Disadvantages
  • Up to 75% of agricultural  would need to be sacrificed if ethanol were to replace petroleum in order to grow the crops required. 
  • The disposal of the large amount of waste produced by fermentation liquors required for ethanol production would present major environmental problems.
  • Massive amounts of Energy are required for the distillation process for the creation of ethanol
  • Currently, fossil fuels are used for the heating and transport, and so the process is not as renewable not "Greenhouse-friendly" as first thought.
  • Entirely new engines are needed to run on pure ethanol. This is not feasible for manufacturers and car  owners.
  • Some car manufacturers opposed concentrations of more than 10% ethanol as it is believed that they could damage car engines.
  • A gallon of ethanol contains less energy than a gallon of gasoline which results in lower fuel economy. The more ethanol in the blend the less energy needed.
  • It is a high octane fuel, it offers increased vehicle power and performance.
  • The release of carbon dioxide contributes to global warming. When the reaction is incomplete either carbon or the toxic carbon monoxide is formed as depicted in the equations below:





Final assessment of the use of ethanol
Ethanol is more expensive than petrol. However, in Australia this is subsided by the government and excise concessions to encourage the production of ethanol from crops have been set up. Car manufacturers have objected to more than 10% concentrations of ethanol. Ethanol is a renewable resource and environmentally friendly, however, the areas of agricultural area which would be over taken and the issues with waste disposal make larger scale use of the product appear unfeasible. 95% of gasoline sold already has some level of ethanol in it. This makes it more environmentally friendly and although it releases less energy,  it offers increased vehicle power and performance as it is a high octane fuel.









Summarises the processes involved in the industrial production of ethanol from sugar cane.

Sugarcane ethanol is an alcohol-based fuel produced by the fermentation of sugarcane juice and molasses. Because it is a clean, affordable and low-carbon bio-fuel, sugarcane ethanol has emerged as a leading renewable fuel for the transportation sector.

At the mill, sugar cane is weighed and processed then moved to a shredder. The shredder breaks apart the cane and juice cells. Rollers are used to separate sugar juice from the fibrous material, called bagasse. The bagasse is extracted and its properties utilised to serve as a fuel for the mill boiler furnaces. The sugarcane juices are then purified before being concentrated as they boil in an evaporator.The process of making sugar cane can be summarised by the following flow chart:


To create ethanol, the sugars must first be fermented. Fermentation is a process in which glucose is converted to ethanol and carbon dioxide by the action of the enzymes in yeast. In order to do this the necessary conditions are that the sugars need to be in solution, yeast containing certain enzymes must be present, a temperature of about 37˚C must be applied and the solution must be deprived from oxygen and hence be in anaerobic conditions. The ethanol produced must then be distilled from the water it is dissolved in.

Enzymes are biological catalysts. They convert the sucrose into glucose and/or fructose. Other enzymes convert glucose or fructose into ethanol and carbon dioxide. This can be represented by the following equation:

Bubbles of carbon dioxide are slowly given off by the process, The yeast can produce ethanol contents of up to 15%. It is then up to fermentation to raise the amount of ethanol to 95%. The ethanol must be subjected to further elaborate distillation processes to make it 100% pure.



Assess the potential of ethanol to be used as an alternative fuel and the advantages and disadvantages of its use

Future of Ethanol
Ethanol is useful as an industrial solvent. Although the ethanol added to gasoline used as a fuel blend presently comes from the fermentation of sugar from crops ethanol could possibly be sourced from ethylene which would make it more economic.Ethanol is the only fuel that can be derived from ethylene via hydration which can be seen in the equation below:

 However,  this would not help in overcoming the global crude oil deficiency. If consistent with the current rates of petroleum usage, within the next 2-3 decades there will no longer be a supply of crude oil. When that time comes an alternative fuel such as as ethanol is likely to replace it.  The future of ethanol is depicted in the following videos:


Assessment on the potential use of Ethanol
By current standards it is implausible to shift the global reliance of petroleum to ethanol. If more engines were built suited to withstand pure ethanol the usage of the fuel would be more likely. For this to happen there would also be a more affordable and less difficult distillation process in order to retrieve ethanol from biomass. Other forms of creating ethanol prove to be problematic,however, if enough agricultural land can be sacrificed and a likely more efficient production process created as well as subsidies on the product and engines with the ability to avoid damage from the ethanol then the use of ethanol appears much more plausible.

Reference List

References

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